秦方汉草HTTP杀菌抗病毒防污水产养殖网箱

摘要Abstract
 
本技术公开了一种秦方汉草杀菌抗病毒防污水产养殖网箱，应用在水产养殖领域中，解决了现有技术中养殖网箱易滋生细菌的技术问题，其技术方案要点是网衣采用含有高分子聚核重组高效杀菌抗病毒防污母粒，以该防污母粒为原材料制成纤维、塑料包覆钢丝或者钢管、塑料制成的镂空板材或者栅板;使得网衣与框架均具有抗菌、防污、耐磨、抗腐蚀性以及具有较高强度、硬度与抗冲击性的深海用养殖网箱的表面防护材料。
The invention discloses a sterilizing, antiviral and antifouling aquaculture net cage of QFHC, which is applied in the field of aquaculture and solves the technical problem of breeding bacteria easily in the cage of the prior art. The key point of the technical scheme is that the net coat adopts a high efficient sterilizing, antiviral and anti-fouling masterbatch containing high molecular aggregation, which is made of fiber, plastic coated steel wire or Hollow plate or grid plate made of steel pipe and plastic, which makes the net coat and frame have antibacterial, anti-fouling, wear-resistant, corrosion-resistant and high strength, hardness and impact resistant surface protective materials for deep sea cage.
 


权利与要求：Application for rights
 
1.一种秦方汉草HPPT杀菌抗病毒防污水产养殖网箱，其特征在于：网衣采用含有HPPT高分子聚核重组高效杀菌抗病毒防污母粒的纤维，或采用含有高分子聚核重组高效杀菌抗病毒防污母粒的塑料包覆的钢丝或钢管，或采用含有HPPT高分子聚核重组高效杀菌抗病毒防污母粒的镂空板材或栅板;框架采用含有HPPT高分子聚核重组高效杀菌抗病毒防污母粒的塑料包覆的金属构件。
1. A kind of HPPT sterilization, antiviral and anti-fouling aquaculture cage, which is characterized in that: the mesh is made of fiber containing HPPT high molecular weight recombinant high-efficiency sterilization, antiviral and anti-fouling masterbatch, or steel wire or steel pipe covered with plastic containing high molecular weight recombinant high-efficiency sterilization, antiviral and anti-fouling masterbatch, or high molecular weight recombinant high-efficiency sterilization, antiviral and anti-fouling masterbatch Hollow plate or grid plate of HPPT particles; the frame is made of plastic coated metal components containing HPPT polymer core recombinant high-efficiency bactericidal, antiviral and anti-fouling masterbatch.
 
2.根据权利与要求1所述的秦方汉草HPPT杀菌抗病毒防污水产养殖网箱，其特征在于，秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒包括如下重量份的组分：复合基体树脂 40~50份、白炭黑 5~10份、PTFE蜡粉 10~15份、抗菌母粒 3~5份、秦方汉草HPOSS改性高分子抗污助剂 3~5份、分散剂 1~3份以及硅烷偶联剂 0.5~2份。
2. The QFHC HPPT sterilization, antiviral and anti-fouling aquaculture cage according to claim 1, which is characterized in that the HPPT polymer core polymer recombinant high-efficiency sterilization, antiviral and anti-fouling master batch comprises the following components by weight: 40-50 parts of composite matrix resin, 5-10 parts of white carbon black, 10-15 parts of PTFE wax powder, 3-5 parts of antibacterial master batch, and HPOSS modified polymer anti-fouling assistant of QFHC 3-5 phr, 1-3 phr of dispersant and 0.5-2 phr of silane coupling agent.
 
3.根据权利与要求2所述的秦方汉草HPPT杀菌抗病毒防污水产养殖网箱，其特征在于：所述复合基体树脂选用PE、PP、ABS、SEBS、CPVC、PMMA、PET、PBT、PA中至少一种。
3. The QFHC HPPT sterilization, antiviral and anti-fouling aquaculture cage according to claim 2, which is characterized in that the composite matrix resin selects at least one of PE, PP, ABS, SEBS, CPVC, PMMA, pet, PBT and PA.
 
4. 根据权利与要求2所述的秦方汉草HPPT杀菌抗病毒防污水产养殖网箱，其特征在于：所述抗菌母粒为含有多元胺和胍盐合成高分子材料充当抗菌助剂的高分子聚核重组材料。
4.  The QFHC HPPT sterilizing, antiviral and anti-fouling aquaculture cage according to claim 2, which is characterized in that the antibacterial masterbatch is a polymer nuclear recombination material containing polyamine and guanidine salt synthetic polymer material as an antibacterial agent.
 
5. 根据权利与要求4所述的秦方汉草HPPT杀菌抗病毒防污水产养殖网箱，其特征在于：所述抗菌助剂的相对分子质量为1500~30000。
5. The QFHC HPPT sterilization, antiviral and anti-fouling aquaculture cage according to claim 4, which is characterized in that the relative molecular weight of the antibacterial agent is 1500-30000.
 
6. 根据权利与要求2所述的秦方汉草HPPT杀菌抗病毒防污水产养殖网箱，其特征在于：所述秦方汉草HPOSS改性高分子抗污助剂包括如下重量份的组分：秦方汉草HPOSS 5~10份、丙烯酸酯类 50~60份、不饱和有机硅20~30份、分散剂 1~3份与硅烷偶联剂 0.5~2份。
6. The QFHC HPPT sterilization, antiviral and anti-fouling aquaculture cage according to claim 2, which is characterized in that: the QFHC HPOSS modified polymer anti-fouling agent comprises the following components by weight: QFHC HPOSS 5-10, acrylate 50-60, unsaturated organic silicon 20-30, dispersant 1-3 and silane coupling agent 0.5-2.
 
7. 根据权利与要求2所述的秦方汉草HPPT杀菌抗病毒防污水产养殖网箱，其特征在于：所述分散剂选用三乙基己基磷酸或者甲基戊醇。
7. The QFHC HPPT sterilization, antiviral and anti-fouling aquaculture cage according to claim 2, which is characterized in that the dispersant is triethylhexyl phosphoric acid or methyl amyl alcohol.
 
8. 根据权利与要求2所述的秦方汉草HPPT杀菌抗病毒防污水产养殖网箱，其特征在于，秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒的制备方法包括如下步骤：
8. The QFHC HPPT sterilization, antiviral and anti-fouling aquaculture cage as claimed in claim 2, which is characterized in that the preparation method of QFHC HPPT polymer polymer core polymer recombinant high-efficiency sterilization, antiviral and anti-fouling masterbatch comprises the following steps:
 
(1)选取复合基体树脂进行混合，辊压时间至少15min，得到混合基体;
(1) The composite matrix resin was selected for mixing, and the rolling time was at least 15 minutes to obtain the mixed matrix;
 
(2)然后在混合基体中添加秦方汉草HPPT抗菌母粒、秦方汉草HPOSS改性高分子抗污助剂进行混合，得到混合体;
(2) Then, the antibacterial masterbatch of QFHC HPPT and the polymer anti-fouling agent modified by QFHC HPOSS were added to the mixed matrix;
 
(3)向混合体中添加白炭黑、PTFE蜡粉与分散剂进行混合，辊压时间至少为2h;
(3) White carbon black, PTFE wax powder and dispersant were added to the mixture, and the rolling time was at least 2 h;
 
(4)加入硅烷偶联剂进行均匀混合;
(4) Adding silane coupling agent for uniform mixing;
 
(5)挤出造粒。
(5) Extrusion granulation.
 
说明书Instructions
 
杀菌抗病毒防污水产养殖网箱
Sterilization, antiviral and antifouling aquaculture cage
 
技术领域Technical field
 
本技术涉及养殖网箱，特别涉及一种杀菌抗病毒防污水产养殖网箱。
The invention relates to an aquaculture cage, in particular to a sterilization, antiviral and antifouling aquaculture cage
 
背景技术Background technology
 
从1999年我国首次从挪威引进大型深海抗风浪网箱设备，深海网箱在我国得到快速发展，后引进更为先进的挪威HDPE网箱和美国海洋站网箱等。从2001年国内自主开发的深海网箱进入投产阶段。
In 1999, China first imported large-scale deep sea anti wind and wave cage equipment from Norway. The deep sea cage has developed rapidly in China, and then introduced more advanced Norwegian HDPE cage and American Ocean Station cage. From 2001, the deep sea cage independently developed in China has entered the stage of production.
 
深海网箱养殖作为一种高密度、集约化养殖方式，在世界上发展十分迅速，并向自动化、多功能化、大型化和外海深水化的方向发展。近年来，频繁发生的大规模死鱼事故，使养殖成为一个巨大的风险行业，特别是在开放连通的水域，不管是海水还是淡水，一旦病毒发生，则是雪崩式的连锁效应;在表面上看，每次大规模死鱼的原因，都是病害或缺氧，但经过观察调研结果来看，则是细菌感染致命。养殖网箱主要由框架、网衣、浮子、沉子与拉索组成，因此，亟待研发具有杀菌抗病毒防污功能的养殖网箱。
Background as a high-density and intensive culture method, the deep-sea cage culture is developing rapidly in the world, and it is developing towards the direction of automation, multi-functional, large-scale and deep-water. In recent years, the frequent occurrence of large-scale dead fish accidents makes aquaculture a huge risk industry, especially in the open and connected waters, whether it is sea water or fresh water, once the virus occurs, it is an avalanche type chain effect; On the surface, the cause of every large-scale dead fish is disease or lack of oxygen, but according to the results of observation and investigation, it is bacterial infection that is fatal. The cage is mainly composed of frame, net coat, float, sinker and cable. Therefore, it is urgent to develop a cage with the function of sterilization, antiviral and antifouling.
 

 
技术内容Summary of the invention
 
本技术的目的是提供一种秦方汉草HPPT杀菌抗病毒防污水产养殖网箱，有助于减少养殖网箱上的细菌滋生，提高养殖过程的安全性、稳定性。
The invention aims to provide a QFHC HPPT bactericidal, antiviral and antifouling aquaculture cage, which is helpful to reduce the bacteria breeding on the cage and improve the safety and stability of the aquaculture process.
 
本技术的上述技术目的是通过以下技术方案得以实现的：
The technical purpose of the invention is realized by the following technical scheme:
 
一种秦方汉草HPPT杀菌抗病毒防污水产养殖网箱，网衣采用含有秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒的纤维，或采用含有高分子聚核重组高效杀菌抗病毒防污母粒的塑料包覆的钢丝或钢管，或采用含有秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒的镂空板材或栅板;框架采用含有秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒的塑料包覆的金属构件。
The utility model relates to a sterilizing, antiviral and antifouling aquaculture net cage of qinfanghancao HPPT. The net cover adopts a fiber containing high molecular weight, recombinant, highly effective sterilizing, antiviral and antifouling masterbatch of qinfanghancao HPPT, or a steel wire or steel pipe covered with plastic containing high molecular weight, recombinant, highly effective sterilizing, antiviral and antifouling masterbatch, or a high molecular weight, recombinant, highly effective sterilizing, antiviral and antifouling masterbatch of qinfanghancao HPPT Hollow plate or grid plate of masterbatch; the frame is made of metal component covered with plastic containing HPPT polymer core recombinant high-efficiency bactericidal, antiviral and antifouling masterbatch.
 
通过采用上述技术方案，对养殖网箱的网衣与框架部分进行抗菌、防腐处理，自制含有秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒，以该防污母粒为原材料制成纤维、塑料等;塑料还可包覆钢丝或者钢管，还可制成镂空板材或栅板;框架采用包覆金属构件的塑料充当，使得网衣与框架均具有抗菌、防污、耐磨、抗腐蚀性以及具有较高强度、硬度与抗冲击性的深海用养殖网箱的表面防护材料。
By adopting the above technical scheme, the net coat and frame part of the cage are treated with anti-bacterial and anti-corrosion treatment, and the self-made high polymer polymer polymer core recombinant high-efficiency anti-bacterial, anti-virus and anti pollution masterbatch containing qinfanghancao HPPT is used as the raw material to make fibers, plastics, etc.; the plastics can also be coated with steel wires or steel pipes, and can also be made into hollow plates or grid plates; The frame is made of plastic coated with metal components, which makes the net coat and frame have antibacterial, antifouling, wear-resistant, corrosion-resistant and high strength, hardness and impact resistant surface protective materials for deep sea cage.
 
本技术进一步设置为The invention is further set as follows:
 
秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒包括如下重量份的组分：复合基体树脂40～50份、白炭黑5～10份、PTFE蜡粉10～15份、HTTP抗菌母粒3～5份、秦方汉草HPOSS改性高分子抗污助剂3～5份、分散剂1～3份以及硅烷偶联剂0.5～2份。
The HPPT high molecular weight composite matrix resin 40-50 parts, silica 5-10 parts, PTFE wax 10-15 parts, HTTP antibacterial masterbatch 3-5 parts, hposs modified polymer antifouling agent 3-5 parts, dispersant 1-3 parts and silane coupling agent 0.5-2 parts.
 
 
通过采用上述技术方案，秦方汉草HPPT抗菌母粒、秦方汉草HPOSS改性高分子抗污助剂等功能填料虽然具有抗菌、防腐、防污作用，但是本身强度、硬度不够，需要借助复合基体树脂作为载体;选取复合基体树脂混配，组成混合基体，兼具韧性和高强度，特别是对交变应力的优良耐疲劳性得到显著提高，可与合金相媲美;混合基体具有优异的耐腐蚀性，能溶解或者破坏的只有浓硫酸，耐腐蚀性与镍钢相近;白炭黑粒度小，比表面积大，表面上带有硅烷醇基团，可与相邻的白炭黑颗粒相互作用而形成氢键，氢键作用使其形成触变形结构，可作为理想的防沉剂，对于防止涂料体系中颜料的沉淀非常有效;同时有助于提高该防污母粒的强度、硬度;PTFE蜡粉为白色粉末，颗粒较细，其分子量仅为PTFE树脂的百分之一，具有结晶度高、分散性好、易于与其他组分混合，能够均匀分布在上述树脂基体内具有良好的分散性能，可获得出众的耐磨、抗划伤性能、耐磨性与耐腐蚀性;杀病毒抗菌母粒可影响细菌的生长分裂、孢子萌发并产生呼吸受到抑制、细胞膨胀、细胞质体的瓦解和细胞壁的破坏等不正常现象，从而达到抑制或杀死生物的目的;秦方汉草HPOSS是由硅氧多元环形成的立方多面体组成，以Si-O键为无机框架，在硅上带有烃基或者极性官能团，能够通过接枝、共聚或者共混引入到高分子抗污助剂中，提高高分子抗污助剂表面的硬度、力学性能、抗氧化性、耐热性、阻燃性和加工流动性，秦方汉草HPOSS是中空的刚性的笼子，密度低而质量轻，气体渗透性好，尤其是对称的笼型，介电性、光学性、抗辐射性以及热稳定性均较好，秦方汉草HPOSS以分子级分散于聚合物中，不会产生相分离，应用于户外高温照射，明显增加共混物的耐候性;向复合基体树脂添加白炭黑、PTFE蜡粉、抗菌母粒、秦方汉草HPOSS改性高分子抗污助剂、分散剂与硅烷偶联剂，发生交联聚合反应，制备具有高硬度、高强度与良好的耐磨性以及优异的杀菌、防腐、耐污性能的防污母粒，以使该防污母粒制成纤维、或者管材、板材等作为网衣、框架的表面防护材料。
By adopting the above technical scheme, the functional fillers such as QFHC HPPT antibacterial masterbatch and QFHC hposs modified polymer antifouling agent have antibacterial, antiseptic and antifouling functions, but their strength and hardness are not enough, so they need to use composite matrix resin as carrier; The mixed matrix is composed of composite matrix resin, which has toughness and high strength, especially the excellent fatigue resistance to alternating stress, which is comparable to that of alloy; the mixed matrix has excellent corrosion resistance, only concentrated sulfuric acid can be dissolved or destroyed, and the corrosion resistance is similar to that of nickel steel; Silica has small particle size, large specific surface area, and silanol group on the surface, which can interact with adjacent silica particles to form hydrogen bond. Hydrogen bond makes it form contact deformation structure. It can be used as an ideal anti sedimentation agent, which is very effective to prevent the precipitation of pigment in the paint system; meanwhile, it can help to improve the strength and hardness of the anti pollution masterbatch; PTFE wax powder is white powder with fine particles and molecular weight only one percent of PTFE resin. It has high crystallinity, good dispersion, easy to mix with other components, and can be evenly distributed in the above resin matrix with good dispersion performance. It can obtain outstanding wear resistance, scratch resistance, wear resistance and corrosion resistance; Virus killing and antibacterial masterbatch can affect the growth and division of bacteria, spore germination and produce abnormal phenomena such as respiratory inhibition, cell expansion, disintegration of cytoplasma and destruction of cell wall, so as to achieve the purpose of inhibiting or killing organisms; Hposs of QFHC is a cubic polyhedron formed by silicon oxygen polyhedron. It takes Si-O bond as inorganic framework and has hydrocarbon or polar functional groups on silicon. It can be grafted, copolymerized or blended into polymer antifouling additive to improve the hardness, mechanical properties, oxidation resistance, heat resistance, flame retardancy and processing fluidity of the surface of polymer antifouling additive Poss is a hollow and rigid cage with low density and light weight, good gas permeability, especially symmetrical cage, good dielectric, optical, radiation resistance and thermal stability. Hposs of QFHC is dispersed in polymer at molecular level, without phase separation, and can be used in outdoor high temperature irradiation, obviously increasing the weather resistance of the blend; Adding silica, PTFE wax powder, antibacterial masterbatch, hposs modified polymer antifouling assistant, dispersant and silane coupling agent to the composite matrix resin, cross-linking polymerization is carried out to prepare antifouling masterbatch with high hardness, high strength and good wear resistance as well as excellent bactericidal, anticorrosive and antifouling performance, so that the antifouling masterbatch can be made into fiber, pipe, plate, etc It is used as the surface protective material of the net clothing and the frame.
 
本技术进一步设置为：所述复合基体树脂选用PE、PP、ABS、SEBS、CPVC、PMMA、PET、PBT、PA中至少一种。
The invention is further arranged that the composite matrix resin selects at least one of PE, PP, ABS, SEBS, CPVC, PMMA, pet, PBT and PA.
 
通过采用上述技术方案，根据不同的使用环境，选择合适的基体材料，基体材料作为各功能性助剂的载体，有利于各功能性助剂更好的发挥各自功能;同时，有助于提高该防污母粒的强度、硬度以及耐磨性，适用于在深海环境中使用。
By adopting the above technical scheme, according to the different use environment, select the appropriate matrix material, the matrix material as the carrier of each functional assistant, which is conducive to the better performance of each functional assistant; at the same time, it is helpful to improve the strength, hardness and wear resistance of the antifouling Masterbatch, which is suitable for use in the deep sea environment.
 
本技术进一步设置为：所述秦方汉草HPPT抗菌母粒为含有多元胺和胍盐合成高分子材料充当抗菌助剂的高分子聚核重组材料。
The invention is further arranged as follows: the QFHC HPPT antibacterial masterbatch is a polymer nuclear recombination material containing polyamine and guanidine salt synthetic polymer material as an antibacterial assistant.
 
通过采用上述技术方案，胍盐具有优异的抗菌性能，因其具有较高的活性，溶于水后带正电荷，故容易吸附在带负电荷的微生物表面，阻碍细胞溶菌酶作用，使细胞表层结构变性而破坏，从而抑制细菌繁殖;胍基团是有效的活性基团，可以与生物体中的基团或元素相互作用，破坏其正常的物质和能量代谢，秦方汉草HPPT杀病毒抗菌母粒采用含多元胺和胍盐的合成高分子材料充当抗菌助剂辅以其他填料制成的高分子聚核重组材料，具有优异的抗菌性能。
By adopting the above technical scheme, guanidine salt has excellent antibacterial performance. Because of its high activity and positive charge after dissolving in water, it is easy to be adsorbed on the surface of microorganism with negative charge, hindering the action of lysozyme, denaturing and destroying the surface structure of cell, thus inhibiting the propagation of bacteria; Guanidine group is an effective active group, which can interact with groups or elements in the organism and destroy its normal material and energy metabolism. The HPPT antivirus masterbatch of QFHC uses the synthetic polymer containing polyamine and guanidine salt as the antibacterial assistant and other fillers to make polymer nuclear recombination material, which has excellent antibacterial performance.
 
本聚核科技进一步设置为：所述HPPT杀病毒抗菌助剂的相对分子质量为1500～30000。
The polynuclear technology is further set as follows: the relative molecular weight of the HPPT virus killing and antibacterial agent is 1500-30000.
 
通过采用上述技术方案，合成的抗菌母粒分子量可控，制备的抗菌助剂，其相对分子质量为1500～30000，根据不同的使用需求，调节适当的相对分子质量，适用场合较广泛。
By adopting the above technical scheme, the molecular weight of the synthesized antibacterial masterbatch can be controlled, and the prepared antibacterial auxiliary has a relative molecular weight of 1500-30000. According to different use needs, the appropriate relative molecular weight can be adjusted, which is widely used.
 
本技术进一步设置为：所述秦方汉草HPOSS改性高分子抗污助剂包括如下重量份的组分：秦方汉草HPOSS 5～10份、丙烯酸酯类50～60份、不饱和有机硅20～30份、分散剂1～3份与硅烷偶联剂0.5～2份。
The invention is further arranged as follows: the hposs modified polymer antifouling agent of QFHC comprises the following components by weight: 5-10 parts of QFHC hposs, 50-60 parts of acrylate, 20-30 parts of unsaturated organosilicon, 1-3 parts of dispersant and 0.5-2 parts of silane coupling agent
 
通过采用上述技术方案，秦方汉草HPOSS具有较好的介电性和光学性能，耐热性、抗辐射性;秦方汉草HPOSS分子交链在高分子抗污助剂上，当温度升高到聚合物开始融化的温度时，秦方汉草HPOSS仍能保持不变，当高温使其表面的有机分子氧化时，对氧稳定的秦方汉草HPOSS链仍保持不变，它们固定住氧化的有机碳黑形成一层耐高温、耐光老化层提供结构支撑，使共混物具有优异的耐盐腐蚀与耐海水冲击性;丙烯酸酯类具有优良的耐候性、成膜性和粘结性，不饱和有机硅具有较强的活性，与丙烯酸酯类发生化学反应，生成的聚合物主链中含有Si-O-Si键、Si-C键，Si-O键，它们的键能远大于C-O键的键能，具有高度的柔顺性、优异的耐高低温性能、耐候性、耐水性，大大提高了丙烯酸酯类的耐溶剂性、耐高低温性能、耐氧化降解性能，同时兼有纯丙稀酸酯的表面能低、憎水、抗污性以及电绝缘性和弹性等优良特性，有效地解决了丙烯酸酯涂膜的缺点和硅溶胶涂膜时存在的刚性强、光泽度低、易龟裂、低温干燥迅速等缺陷，二者可以达到性能上的优势互补。
By adopting the above technical scheme, hposs has better dielectric and optical properties, heat resistance and radiation resistance; When the temperature rises to the temperature when the polymer begins to melt, the hposs of QFHC will remain unchanged. When the high temperature makes the organic molecules on its surface oxidized, the hposs chain of QFHC will remain unchanged. They fix the oxidized organic carbon black to form a high temperature and light resistant aging layer to provide structural support, The blends have excellent salt corrosion resistance and seawater impact resistance; Acrylates have excellent weatherability, film-forming property and adhesive property. Unsaturated organosilicon has strong activity. It reacts with acrylates. The main chain of the polymer contains Si-O-Si bond, Si-C bond and Si-O bond. Their bond energy is far greater than that of C-O bond. They have high flexibility, excellent high and low temperature resistance, weatherability and water resistance, greatly improving The properties of acrylates, such as solvent resistance, high and low temperature resistance, oxidation resistance and degradation resistance, as well as the excellent properties of pure propionate, such as low surface energy, hydrophobicity, antifouling, electrical insulation and elasticity, have effectively solved the shortcomings of acrylates film and the defects such as strong rigidity, low gloss, easy cracking, rapid drying at low temperature, etc. existing in the silicone sol film Complementary to performance.
本科技进一步设置为：所述分散剂选用三乙基己基磷酸或者甲基戊醇。
The technology is further set as follows: the dispersant is triethylhexyl phosphoric acid or methyl amyl alcohol.
 
通过采用上述技术方案，三乙基己基磷酸和甲基戊醇均是性能优异的分散剂，能够降低分散体系中固体或液体粒子聚集的物质，保持体系中的稳定性，三乙基己基磷酸或者甲基戊醇添加到反应体系内，使反应体系中的各组分能够更均匀地进行分散，有助于反应地更加充分、彻底。
By adopting the above technical scheme, triethylhexyl phosphoric acid and methylamyl alcohol are excellent dispersants, which can reduce the aggregation of solid or liquid particles in the dispersion system, maintain the stability of the system, and add triethylhexyl phosphoric acid or methylamyl alcohol to the reaction system, so that the components in the reaction system can be more evenly dispersed, which is conducive to more reaction Fully and thoroughly.
本科技进一步设置为：秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒的制备方法包括如下步骤：
The technology is further set up as follows: the preparation method of HPPT polymer recombinant high efficient bactericidal, antiviral and antifouling masterbatch of QFHC includes the following steps:
 
(1)选取复合基体树脂进行混合，辊压时间至少15min，得到混合基体;
(1) The composite matrix resin was selected for mixing, and the rolling time was at least 15 minutes to obtain the mixed matrix;
(2)然后在混合基体中添加抗菌母粒、秦方汉草HPOSS改性高分子抗污助剂进行混合，得到混合体;
(2) Then the antibacterial masterbatch and hposs modified polymer antifouling agent were added to the mixed matrix to obtain the mixture;
(3)向混合体中添加白炭黑、PTFE蜡粉与分散剂进行混合，辊压时间至少为2h;
(3) White carbon black, PTFE wax powder and dispersant were added to the mixture, and the rolling time was at least 2 h;
(4)加入硅烷偶联剂进行均匀混合;
(4) Adding silane coupling agent for uniform mixing;
(5)挤出造粒。
(5) Extrusion granulation.
通过采用上述技术方案，首先将防污母粒中的各组分进行均匀混合，混合时在混合基体中先添加抗菌母粒、秦方汉草HPOSS改性高分子抗污助剂，待其均匀渗透在混合基体中，然后再与其他粉状填料白炭黑、PTFE蜡粉等均匀混合，具有良好的相容性，且混合均匀，最后对均匀的混合体挤出造粒。
By adopting the above technical scheme, firstly, all components in the antifouling masterbatch are evenly mixed. When mixing, the antibacterial masterbatch and hposs modified polymer antifouling agent are added to the mixed matrix, and then they are evenly mixed with other powder fillers, such as white carbon black and PTFE wax powder, with good compatibility and even mixing. Finally Extrude and granulate the homogeneous mixture.
 
综上所述，本科技技术具有以下有益效果：
In conclusion, this technology has the following beneficial effects:
 
1、本技术提供了秦方汉草HPPT杀菌抗病毒防污水产养殖网箱，显著减少了在养殖网箱上滋生的细菌，使制备的养殖网箱具有杀菌、抗腐蚀、耐污的性能;
1. The invention provides an HPPT sterilizing, antiviral and antifouling aquaculture cage of QFHC, which significantly reduces the bacteria growing on the cage, and enables the prepared cage to have the performance of sterilization, corrosion resistance and pollution resistance;
 
2、由于该养殖网箱的适用场所为深海区域，本技术的养殖网箱还具有较高的强度、硬度以及优异的耐磨、抗冲击性;
2. Because the suitable place of the cage is the deep sea area, the cage of the invention also has high strength, hardness, excellent wear resistance and impact resistance;
 
3、本科技的填料白炭黑除具有增强功能外，还具有防沉降的作用，有助于白炭黑、PTFE蜡粉等的均匀分散;
3. In addition to the enhancement function, the filler silica of this technology also has the function of anti settling, which is helpful for the uniform dispersion of silica and PTFE wax powder;
 
4、首先对基体进行改性，配制复合基体树脂形成混合基体，然后将抗菌母粒、秦方汉草HPOSS改性高分子抗污助剂均匀渗透在混合基体中，抗菌母粒与秦方汉草HPOSS改性高分子抗污助剂会发生协同作用，有助于各功能组分发挥功能作用。
4. Firstly, the matrix was modified to prepare composite matrix resin to form a mixed matrix, and then the antibacterial masterbatch and hposs modified polymer antifouling agent of QFHC were permeated into the mixed matrix evenly. The antibacterial masterbatch and hposs modified polymer antifouling agent of QFHC will work together, which is helpful for the functional components to play their roles.
 


具体实施方式
Specific implementation mode
 
以下结合实施例对本技术作进一步详细说明。
The invention will be described in further detail in combination with the embodiments.
 
实施例一：
制备秦方汉草HPPT杀病毒抗菌母粒，具体步骤为：(1)取乙二胺100g，碳酸胍190g，加入到500ml三颈瓶中，在氮气保护下，搅拌并升温至100℃，反应1小时;(2)然后升温至190℃反应8小时;(3)再加入15g马来酸酐，10分钟后结束反应，得到抗菌助剂，数均分子量平均为1500;(4)称取30g抗菌助剂、PE塑料60g、白炭黑7g以及分散剂3g进行挤出造粒。
Embodiment 1:
The specific steps of preparation of QFHC HPPT antivirus masterbatch are as follows: (1) take 100g of ethylenediamine and 190g of guanidine carbonate, add them into a 500ml three necked bottle, under the protection of nitrogen, stir them and heat them to 100 ℃ for 1 hour; (2) then heat them to 190 ℃ for 8 hours; (3) add 15g of maleic anhydride again, and finish the reaction after 10 minutes, and obtain antibacterial additives, with average molecular weight of 1500; (4) Weigh 30g antibacterial agent, 60g PE plastic, 7g white carbon black and 3G dispersant for extrusion granulation.
 
实施例二：
制备秦方汉草HPPT杀病毒抗菌母粒，具体步骤为：(1)取己二胺100g，硝酸胍110g，加入到500ml三颈瓶中，在氮气保护下，搅拌并升温至140℃，反应2小时;(2)然后升温至210℃反应6小时;(3)再加入10g丙烯酸，15分钟后结束反应，得到抗菌助剂，数均分子量平均为2800;(4)称取30g抗菌助剂、PE塑料60g、白炭黑7g以及分散剂3g进行挤出造粒。
Embodiment 2:
The specific steps of preparing HPPT antibacterial masterbatch of QFHC are as follows: (1) take 100g of hexanediamine and 110g of guanidine nitrate, add them into a 500ml three necked bottle, stir them under the protection of nitrogen, heat them up to 140 ℃ and react for 2 hours; (2) heat them up to 210 ℃ and react for 6 hours; (3) add 10g of acrylic acid, and finish the reaction 15 minutes later, and get the antibacterial assistant, whose average molecular weight is 2800; (4) Weigh 30g antibacterial agent, 60g PE plastic, 7g white carbon black and 3G dispersant for extrusion granulation.
 
实施例三：
制备秦方汉草HPPT杀病毒抗菌母粒，具体步骤为：(1)取六次甲基四胺100g，磷酸胍310g，加入到500ml三颈瓶中，在氮气保护下，搅拌并升温至150℃，反应5小时;(2)然后升温至230℃反应4小时，再加入40g衣康酸，100分钟结束反应，得到抗菌助剂，数均分子量平均为30000;(4)称取30g抗菌助剂、PE塑料60g、白炭黑7g以及分散剂3g进行挤出造粒。
Embodiment 3:
Preparation of QFHC HPPT antivirus masterbatch, the specific steps are: (1) take 100g of hexamethylenetetramine and 310G of guanidine phosphate, add them into a 500ml three necked bottle, under the protection of nitrogen, stir and heat up to 150 ℃, reaction for 5 hours; (2) then heat up to 230 ℃, reaction for 4 hours, add 40g of itaconic acid, and finish the reaction in 100 minutes, and get antibacterial agent, the average molecular weight of the number is 30000; (4) Weigh 30g antibacterial agent, 60g PE plastic, 7g white carbon black and 3G dispersant for extrusion granulation.
 
实施例四：
制备秦方汉草HPOSS改性高分子抗污助剂，具体步骤为：(1)取丙烯酸甲酯20g、丙烯酸乙酯30g加入到三口烧瓶中，经油浴加热至60℃，搅拌速度为80r/min，搅拌时间为15min;(2)向三口烧瓶中加入乙烯基三甲氧基硅烷20g，搅拌速度为120r/min;(3)缓慢加入秦方汉草HPOSS 5g、三乙基己基磷酸1g;(4)继续加入0.5gγ-氨基丙基三乙氧基硅烷进行搅拌，反应2h，得到秦方汉草HPOSS改性高分子抗污助剂。
Example 4:
To prepare QFHC HPOSS modified polymer antifouling agent of QFHC, the specific steps are as follows:The specific steps are: (1) add 20g of methyl acrylate and 30g of ethyl acrylate into a three port flask, heat to 60 ℃ by oil bath, stirring speed is 80R / min, stirring time is 15min; (2) add 20g of vinyl trimethoxysilane into the three port flask, stirring speed is 120r / min; (3) Slowly add 5g of QFHC hposs and 1g of triethylhexyl phosphoric acid; (4) continue to add 0.5g of γ - aminopropyltriethoxysilane for stirring, and react for 2h to obtain the hposs modified polymer anti pollution additive.
 
实施例五：
制备秦方汉草HPOSS改性高分子抗污助剂，具体步骤为：(1)取丙烯酸甲酯25g、甲基丙烯酸羟乙酯25g加入到三口烧瓶中，经油浴加热至70℃，搅拌速度为100r/min，搅拌时间为15min;(2)向三口烧瓶中加入乙烯基三乙氧基硅烷22g，搅拌速度为120r/min;(3)缓慢加入秦方汉草HPOSS 7g、三乙基己基磷酸1g;(4)继续加入0.8g氨基丙基三甲氧基硅烷进行搅拌，反应2h，得到秦方汉草HPOSS改性高分子抗污助剂。
Example 5:
Preparation of QFHC HPOSS modified polymer antifouling agent is as follows: (1) 25g of methyl acrylate and 25g of hydroxyethyl methacrylate are added into three flask, heated to 70 ℃ by oil bath, stirring speed is 100r / min, stirring time is 15min; (2) 22G of vinyl triethoxysilane is added into three flask, stirring speed is 120r / min; (3) Slowly add 7g of QFHC HPOSS and 1g of triethylhexyl phosphoric acid; (4) continue to add 0.8g of aminopropyltrimethoxysilane for stirring, and react for 2h to obtain the hposs modified polymer anti pollution additive.
 
实施例六：
制备秦方汉草HPOSS改性高分子抗污助剂，具体步骤为：(1)取丙烯酸甲酯20g、甲基丙烯酸羟乙酯35g加入到三口烧瓶中，经油浴加热至70℃，搅拌速度为100r/min，搅拌时间为15min;(2)向三口烧瓶中加入乙烯基三乙氧基硅烷25g，搅拌速度为120r/min;(3)缓慢加入秦方汉草HPOSS 8g、三乙基己基磷酸2g;(4)继续加入1g氨基丙基三甲氧基硅烷进行搅拌，反应2h，得到秦方汉草HPOSS改性高分子抗污助剂。
Example 6:
Preparation of QFHC. HPOSS modified polymer antifouling agent. The specific steps are: (1) add 20g of methyl acrylate and 35g of hydroxyethyl methacrylate into three flask, heat to 70 ℃ by oil bath, stirring speed is 100r / min, stirring time is 15min; (2) add 25g of vinyl triethoxysilane into three flask, stirring speed is 120r / min; (3) Slowly add 8g of qinfanghancao HPOSS and 2G of triethylhexyl phosphoric acid; (4) continue to add 1g of aminopropyltrimethoxysilane for stirring, and react for 2h to obtain the HPOSS modified polymer anti pollution additive.
 
实施例七：
制备秦方汉草HPOSS改性高分子抗污助剂，具体步骤为：(1)取丙烯酸甲酯25g、丙烯酸乙酯30g加入到三口烧瓶中，经油浴加热至70℃，搅拌速度为100r/min，搅拌时间为15min;(2)向三口烧瓶中加入乙烯基三乙氧基硅烷28g，搅拌速度为120r/min;(3)缓慢加入秦方汉草HPOSS 9g、三乙基己基磷酸2g;(4)继续加入1.5g氨基丙基三甲氧基硅烷进行搅拌，反应2h，得到秦方汉草HPOSS改性高分子抗污助剂。
Example 7:
Preparation of HPOSS modified polymer antifouling agent of qinfanghancao is as follows: (1) 25 g of methyl acrylate and 30 g of ethyl acrylate are added into three flask, heated to 70 ℃ by oil bath, stirring speed is 100 R / min, stirring time is 15 min; (2) 28 g of vinyl triethoxysilane is added into three flask, stirring speed is 120 R / min; (3) Slowly add 9g of qinfanghancao HPOSS and 2G of triethylhexyl phosphoric acid; (4) continue to add 1.5g of aminopropyltrimethoxysilane for stirring, and react for 2h to obtain the HPOSS modified polymer anti pollution additive.
 
实施例八：
制备秦方汉草HPOSS改性高分子抗污助剂，具体步骤为：(1)取丙烯酸甲酯20g、丙烯酸乙酯40g加入到三口烧瓶中，经油浴加热至70℃，搅拌速度为100r/min，搅拌时间为15min;(2)向三口烧瓶中加入乙烯基三乙氧基硅烷30g，搅拌速度为120r/min;(3)缓慢加入秦方汉草HPOSS 10g、三乙基己基磷酸3g;(4)继续加入2g氨基丙基三甲氧基硅烷进行搅拌，反应2h，得到秦方汉草HPOSS改性高分子抗污助剂。
Example 8:
To prepare QFHC HPOSS modified polymer antifouling agent , the specific steps are as follows: (1) add 20g of methyl acrylate and 40g of ethyl acrylate into a three port flask, heat to 70 ℃ by oil bath, stir at a speed of 100r / min, and stir for 15min; (2) add 30g of vinyl triethoxysilane into the three port flask, stir at a speed of 120r / min; (3) Slowly add 10g of HPOSS and 3G of triethylhexyl phosphoric acid; (4) continue to add 2G of aminopropyltrimethoxysilane for stirring, and react for 2h to obtain HPOSS modified high molecular anti pollution additive.
 
实施例九：
制备秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒，具体步骤为：(1)配料：PE 40g、ABS 15g、白炭黑5g、PTFE蜡粉10g、抗菌母粒3g、秦方汉草HPOSS改性高分子抗污助剂3g、三乙基己基磷酸1g以及硅烷偶联剂0.5g;(2)将PE、ABS进行混合，辊压时间至少为15min，得到混合基体;(3)然后在混合基体中添加抗菌母粒、秦方汉草HPOSS改性高分子抗污助剂进行混合，得到混合体;(4)向混合体中添加白炭黑、PTFE蜡粉与三乙基己基磷酸进行混合，辊压时间为2h;(5)加入硅烷偶联剂进行均匀混合;(6)挤出造粒。
Example 9:
The main steps are as follows: (1) ingredients: PE 40g, ABS 15g, silica 5g, PTFE wax 10g, antibacterial masterbatch 3G, HPOSS modified polymer antifouling agent 3G, triethylhexylphosphoric acid 1g and silane coupling agent 0.5g; (2) PE and ABS were mixed for at least 15 minutes to obtain the mixed matrix; (3) antibacterial masterbatch and HPOSS modified polymer antifouling agent were added to the mixed matrix to obtain the mixture; (4) silica, PTFE wax powder and triethylhexyl phosphoric acid were added to the mixture for 2 hours; (5) silane coupling agent was added to evenly mix; (6) Extrusion granulation
 
实施例十：
制备秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒，具体步骤为：(1)配料：PP 43g、PET18g、白炭黑6g、PTFE蜡粉11g、抗菌母粒3g、秦方汉草HPOSS改性高分子抗污助剂3g、三乙基己基磷酸1g以及硅烷偶联剂0.8g;(2)将PP、PET进行混合，辊压时间至少为15min，得到混合基体;(3)然后在混合基体中添加抗菌母粒、秦方汉草HPOSS改性高分子抗污助剂进行混合，得到混合体;(4)向混合体中添加白炭黑、PTFE蜡粉与三乙基己基磷酸进行混合，辊压时间为2h;(5)加入硅烷偶联剂进行均匀混合;(6)挤出造粒。
Example 10:
The main steps are as follows: (1) ingredients: PP 43g, pet18g, silica 6G, PTFE wax 11g, antibacterial masterbatch 3G, HPOSS modified polymer antifouling agent 3G, triethylhexyl phosphate 1g and silane coupling agent 0.8g; (2) PP and pet were mixed and rolled for at least 15min to obtain the mixed matrix; (3) Then, antibacterial masterbatch and HPOSS modified polymer antifouling agent were added to the mixed matrix to obtain the mixture; (4) silica and PTFE wax powder were added to the mixture to mix with triethylhexyl phosphoric acid for 2 h; (5) silane coupling agent was added to mix evenly; (6) extrusion granulation.
 
实施例十一：
制备秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒，具体步骤为：(1)配料：PP 45g、PA20g、白炭黑8g、PTFE蜡粉13g、抗菌母粒3g、秦方汉草HPOSS改性高分子抗污助剂3g、三乙基己基磷酸1g以及硅烷偶联剂1g;(2)将PP、PA进行混合，辊压时间至少为15min，得到混合基体;(3)然后在混合基体中添加抗菌母粒、秦方汉草HPOSS改性高分子抗污助剂进行混合，得到混合体;(4)向混合体中添加白炭黑、PTFE蜡粉与三乙基己基磷酸进行混合，辊压时间为2h;(5)加入硅烷偶联剂进行均匀混合;(6)挤出造粒。
Example 11:
The main steps are as follows: (1) ingredients: PP 45g, pa20g, silica 8g, PTFE wax 13g, antibacterial masterbatch 3G, HPOSS modified polymer antifouling agent 3G, triethylhexylphosphoric acid 1g and silane coupling agent 1g; (2) PP and PA were mixed for at least 15min to obtain the mixed matrix; (3) Then, antibacterial masterbatch and HPOSS modified polymer antifouling agent were added to the mixed matrix to obtain the mixture; (4) silica and PTFE wax powder were added to the mixture to mix with triethylhexyl phosphoric acid for 2 h; (5) silane coupling agent was added to mix evenly; (6) extrusion granulation.
 
实施例十二：
制备秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒，具体步骤为：(1)配料：ABS 48g、SEBS 22g、白炭黑9g、PTFE蜡粉14g、抗菌母粒4g、秦方汉草HPOSS改性高分子抗污助剂4g、甲基戊醇2g以及硅烷偶联剂1.5g;(2)将ABS、SEBS进行混合，辊压时间至少为15min，得到混合基体;(3)然后在混合基体中添加抗菌母粒、秦方汉草HPOSS改性高分子抗污助剂进行混合，得到混合体;(4)向混合体中添加白炭黑、PTFE蜡粉与甲基戊醇进行混合，辊压时间为2h;(5)加入硅烷偶联剂进行均匀混合;(6)挤出造粒。
Example 12:
The main steps are as follows: (1) ingredients: ABS 48g, SEBS 22G, silica 9g, PTFE wax 14g, antibacterial masterbatch 4G, HPOSS modified polymer antifouling agent 4G, methylpentanol 2G and silane coupling agent 1.5g; (2) ABS and SEBS were mixed and rolled for at least 15min to obtain the mixed matrix; (3) Then, antibacterial masterbatch and HPOSS modified polymer antifouling agent were added to the mixed matrix to obtain the mixture; (4) silica and PTFE wax powder were added to the mixture to mix with methyl pentanol for 2 h; (5) silane coupling agent was added to mix evenly; (6) extrusion granulation.
 
实施例十三：
制备秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒，具体步骤为：(1)配料：PET 48g、PA 25g、白炭黑10g、PTFE蜡粉15g、抗菌母粒5g、秦方汉草HPOSS改性高分子抗污助剂5g、甲基戊醇3g以及硅烷偶联剂2g;(2)将PET、PA进行混合，辊压时间至少为15min，得到混合基体;(3)然后在混合基体中添加抗菌母粒、秦方汉草HPOSS改性高分子抗污助剂进行混合，得到混合体;(4)向混合体中添加白炭黑、PTFE蜡粉与甲基戊醇进行混合，辊压时间为2h;(5)加入硅烷偶联剂进行均匀混合;(6)挤出造粒。
Example 13:
The main steps are as follows: (1) pet 48g, PA 25g, silica 10g, PTFE wax 15g, antibacterial masterbatch 5g, HPOSS modified polymer antifouling agent 5g, methylpentanol 3G and silane coupling agent 2G; (2) pet and PA were mixed and rolled for at least 15min to obtain the mixed matrix; (3) Then, antibacterial masterbatch and HPOSS modified polymer antifouling agent were added to the mixed matrix to obtain the mixture; (4) silica and PTFE wax powder were added to the mixture to mix with methyl pentanol for 2 h; (5) silane coupling agent was added to mix evenly; (6) extrusion granulation.
 
实施例十四：
秦方汉草HPPT杀菌抗病毒防污水产养殖网箱，网衣采用含有秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒的纤维编织形成;框架采用含有秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒的塑料包覆的金属构件;其中秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒采用实施例九所制备的防污母粒。
Example 14:
Qinfanghancao HPPT sterilizing, antiviral and antifouling aquaculture cage, the net cover is woven with fiber containing qinfanghancao HPPT polymer core, high-efficiency sterilizing, antiviral and antifouling masterbatch; the frame is made of plastic coated metal components containing qinfanghancao HPPT polymer core, high-efficiency sterilizing, antiviral and antifouling masterbatch; Among them, the HPPT high molecular weight recombinant high efficient bactericidal, antiviral and antifouling masterbatch of qinfanghancao was prepared by Example 9.
 
实施例十五：
秦方汉草HPPT杀菌抗病毒防污水产养殖网箱，网衣采用含有秦方汉草HPPT高分子HPPT聚核重组高效杀菌抗病毒防污母粒的塑料包覆的钢丝;框架采用含有秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒的塑料包覆的金属构件;其中秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒采用实施例十所制备的防污母粒。
Example 15:
Qinfanghancao HPPT sterilizing, antiviral and antifouling aquaculture cage is made of steel wire covered by plastic containing qinfanghancao HPPT polymer HPPT recombinant high-efficiency sterilizing, antiviral and antifouling masterbatch; the frame is made of metal components covered by plastic containing qinfanghancao HPPT polymer recombinant high-efficiency sterilizing, antiviral and antifouling masterbatch; Among them, qinfanghancao HPPT high molecular nuclear polymer recombinant high-efficiency bactericidal, antiviral and antifouling masterbatch was prepared by example 10.
 
实施例十六：
秦方汉草HPPT杀菌抗病毒防污水产养殖网箱，网衣采用含有秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒的镂空板材;框架采用含有秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒的塑料包覆的金属构件;其中秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒采用实施例十一所制备的防污母粒。
Example 16:
Qinfanghancao HPPT sterilizing, antiviral and antifouling aquaculture cage is made of hollow plate containing qinfanghancao HPPT polymer core, high efficient sterilizing, antiviral and antifouling masterbatch; the frame is made of plastic coated metal components containing qinfanghancao HPPT polymer core, high efficient sterilizing, antiviral and antifouling masterbatch; Among them, qinfanghancao HPPT high molecular nuclear polymer recombinant high-efficiency bactericidal, antiviral and antifouling masterbatch was prepared by example 11.
 
实施例十七：
秦方汉草HPPT杀菌抗病毒防污水产养殖网箱，网衣采用含有高分子聚核重组高效杀菌抗病毒防污母粒的纤维编织形成;框架采用含有高分子聚核重组高效杀菌抗病毒防污母粒的塑料包覆的金属构件;其中秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒采用实施例十二所制备的防污母粒。
Example 17:
Qinfanghancao HPPT sterilization, antiviral and antifouling aquaculture cage, the mesh is woven with fiber containing high polymer core recombinant high-efficiency sterilization, antiviral and antifouling masterbatch; the frame is made of metal components covered with plastic containing high polymer core recombinant high-efficiency sterilization, antiviral and antifouling masterbatch; Among them, HPPT high molecular weight recombinant high-efficiency bactericidal, antiviral and antifouling masterbatch of qinfanghancao was prepared by example 12.
 
实施例十八：
秦方汉草HPPT杀菌抗病毒防污水产养殖网箱，网衣采用含有秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒的纤维编织形成;框架采用含有秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒的塑料包覆的金属构件;其中秦方汉草HPPT高分子聚核重组高效杀菌抗病毒防污母粒采用实施例十三所制备的防污母粒。
Example 18:
Qinfanghancao HPPT sterilizing, antiviral and antifouling aquaculture cage, the net cover is woven with fiber containing qinfanghancao HPPT polymer core, high-efficiency sterilizing, antiviral and antifouling masterbatch; the frame is made of plastic coated metal components containing qinfanghancao HPPT polymer core, high-efficiency sterilizing, antiviral and antifouling masterbatch; Among them, qinfanghancao HPPT high molecular nuclear polymer recombinant high efficient bactericidal, antiviral and antifouling masterbatch was prepared by example 13.
 
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